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The useful fact about these two substances is that at normal temperatures, potassium is a solid, but argon is a gas.
Therefore, during volcanic eruptions, any argon that is present escapes from the rock.
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Potassium-argon dating is a method for estimating the age of volcanic rocks by measuring the ratio of potassium-40 to argon-40 present.
The method is based on the fact that the potassium-40 isotope of potassium decays over time to form argon-40.